Fused aromatic networks with the different spatial arrangement of structural units
نویسندگان
چکیده
Fused aromatic networks (FANs) are a new generation of porous organic (PONs), which thermodynamic products. FANs also kinetic products with low crystallinity. Nevertheless, their high physicochemical stability suggests many potential applications. This work reports three structures fully fused units vertically (V), horizontally (H), and three-dimensionally (3D) linked to the growth direction, forming “standing” FAN (VS-FAN), “planar” (HP-FAN), 3D-FAN, respectively. Their performance as sorbent materials was evaluated. While VS-FAN has fastest kinetics for CH 4 I 2 adsorption due highest segmental freedom, HP-FAN exhibits best separation selectivity /N mixture strongest confinement. The 3D-FAN displays capacity because specific surface area. results suggest that different arrangements may critically affect FANs. vertically, horizontally, As materials, standing Horizontally planar gas Three-dimensionally arranged shows Is there difference in characteristics depending on polymer direction monomer symmetry? Kim et al. design 2D, 3D based symmetry show properties according structures.
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ژورنال
عنوان ژورنال: Cell reports physical science
سال: 2021
ISSN: ['2666-3864']
DOI: https://doi.org/10.1016/j.xcrp.2021.100502